Schilde Publikationen

PD Dr. habil. Uwe Schilde

Publication list

Books:

1. U. Schilde: Introduction in BASIC for the solution of chemical problems.
Parts I und II. Lehrmaterial. WTZ-Druck. Potsdam 1987.

2. E. Uhlemann u.a.: Praktikum zur Allgemeinen und Anorganischen Chemie.
Reihe Chemie für Lehrer. Deutscher Verlag der Wissenschaften, Berlin 1991. (Mitautor)

Papers:

3. U. Schilde und F.Thier: Polarographie - Eine Einführung in das Praktikum.
Diplomarbeit Leipzig 1976.

4.    L. Beyer, F. Dietze, U. Schilde, K. Schöne und F. Thier: Einsatz des hochschulinternen
       Fernsehens im Chemiestudium. Vorbereitung eines experimentellen Praktikumsabschnittes.
       Wiss. Z. Karl-Marx-Univ. Leipzig, Math.-Naturwiss. R. 26 (1977) 81-84.

5. U. Schilde: Nutzung guter Erfahrungen für den Fachunterricht.
BioS 29 (1980) 257-258.

6.    U. Schilde: Complex formation and extraction properties of alkyl- und alkenyl-
       substituted 8-quinolinols for nickel(II) und copper(II).
       Dissertation, Potsdam 1984.

7.    E. Uhlemann, B. Opitz, U. Schilde, M. Raab und W. Kalies: Chelates of 8-quinolinol
       derivatives. V. Coordination and extraction of nickel with alkyl-substituted 8-quinolinols.
       Z. anorg. allg. Chem. 520 (1985) 167-178.

8.    E. Uhlemann, U. Schilde, R. Kirmse und J. Stach: Chelates of 8-quinolinol derivatives.
       VI. Complex formation and extraction of copper with alkyl and alkenyl substituted
       8-quinolinols.
       Z. anorg. allg. Chem. 524 (1985) 193-200.

9.    A. Friedrich, U. Schilde, E. Uhlemann, R. Szargan und W. Kalies: Chelates of 8-quinolinol
       derivatives. VII. Structure of cobalt oxinate.
       Z. Chem. 25 (1985) 379-380.

10. A. Friedrich, U. Schilde und E. Uhlemann: Chelates of 8-quinolinol derivatives. VIII. Acid
and complex stability constants of alkyl and alkenyl substituted 8-quinolinols.
Z. anorg. allg. Chem. 534 (1986) 199-205.

11. E. Uhlemann, U. Schilde, R. Szargan und S. Ullmann: Structural peculiarities of the nickel
chelates with alkyl substituted 8-quinolinols and -thiols.
Z. Chem. 27 (1987) 303-304.

12. U. Schilde und A. Hanke: KC-85/2(/3)-Tip.
FA 55 (1988) 106.

13. U. Schilde, E. Uhlemann, u.a.: Pat. DD 286.565 (1989/1991).

14. U. Schilde and E. Uhlemann: Extraction of boric acid from brines by ion exchange.
Int. J. Miner. Process. 32 (1991) 295-309.

15. U. Schilde and E. Uhlemann: A simple method for the control of ion exchange processes
with boric acid using specific chelating resins.
React. Polym. 18 (1992) 155-158.

16. E. Ludwig, U. Schilde, E. Uhlemann, F. Weller und K. Dehnicke: Complexes of vanadium
       and titanium with salicylaldehyde benzoylhydrazone and 2-(2'-hydroxyphenyl)-8-quinolinol.
       Crystal structure of .mu.-oxo-bis[oxo{2-(2'-hydroxyphenyl)-8-quinolinolato(2-)}-
       vanadium(V)].
       Z. anorg. allg. Chem. 619 (1993) 669-674.

17. U. Schilde and E. Uhlemann: Separation of several oxoanions with a special chelating resin
containing methylamino-glucitol groups.
React. Polym. 20 (1993) 181-188.

18. U. Schilde: Zur Abtrennung von Oxoanionen mittels chelatbildender Ionenaustauscher.
Habilitationsschrift, Potsdam 1993.

19. E. Ludwig, H. Hefele, U. Schilde und E. Uhlemann: Complexes of vanadium and titanium
       with 2,2'-dihydroxyazobenzene. Crystal structure of 2,2'-dihydroxyazobenzenato(2-)
       oxomethoxo(methanol)vanadium(V) and .mu.-oxobis(2,2'-dihydroxyazobenzenato(2-)
       oxovanadium(V)].
       Z. anorg. allg. Chem. 620 (1994) 346-352.

20. E. Uhlemann, W. Bansse, E. Ludwig, U. Schilde, F. Weller und A. Lehmann: Template
reaction of bis(acetylacetonato)dioxomolybdenum(VI) with benzoylhydrazide.
Z. anorg. allg. Chem. 620 (1994) 357-360.

21. U. Schilde, H. Kraudelt and E. Uhlemann: Separation of the oxoanions of germanium, tin,
       arsenic, antimony, tellurium, molybdenum and tungsten with a special chelating resin
       containing methylaminoglucitol groups.
       React. Polym. 22 (1994) 101-106.

22. U. Schilde, H. Hefele, E. Ludwig und E. Uhlemann: Crystal and molecular structure of
2,2'-dihydroxyazobenzene.
Cryst. Res. Technol. 29 (1994) 393-396.

23. U. Schilde, H. Kraudelt and E. Uhlemann: Sorption of coinage metal cyano complexes by
a chelating resin containing amino-glucitol groups.
React. Polym. 23 (1994) 131-133.

24. E. Uhlemann, U. Schilde und F. Weller: Calcium and barium complexes with 1-phenyl-
3-methyl-4-benzoyl-5-pyrazolone.
Z. Naturforsch. 50b (1995) 31-36.

25. E. Ludwig, H. Hefele, A. Friedrich, B. Kallies, U. Schilde, E. Uhlemann und E. Hahn:
       Reactions and thermal behavior of nonoxo vanadium(IV) complexes. Crystal structures
       of methoxo-oxo[thenoyltrifluoroacetone-salicylhydrazonato(2-)]vanadium(V) and
       methoxo-oxo[benzoylacetone-salicylhydrazonato(2-)]vanadium(V).
       Z. anorg. allg. Chem. 621 (1995) 488-494.

26. E. Uhlemann, A. Friedrich, G. Hinsche, W. Mickler und U. Schilde: Complex formation
       and metal extraction with heterocyclic .beta.-dicarbonyl compounds in comparison.
       Structure of 3-phenyl-4-benzoyl-5-isoxazolone.
       Z. Naturforsch. 50b (1995) 37-42.

27. U. Schilde, H. Kraudelt, E. Uhlemann and U. Gohlke: Selectivity of amidoxime polymers
for the sorption of gallate.
Sep. Sci. & Technol. 30 (1995) 2245-2250.

28. U. Schilde, W. Bansse, E. Ludwig and E. Uhlemann: Crystal structure of bis(1,3-diphenyl-
propane-1,3-dionato)oxo-vanadium(IV).
Z. Kristallogr. 210 (1995) 627-628.

29. W. Bansse, E. Ludwig, U. Schilde, E. Uhlemann, F. Weller und A. Lehmann: Ligand
       exchange reactions of bis(acetylacetonato)dioxomolybdenum(VI). Crystal structures of
       [salicylaldehyde benzoylhydrazonato(2-)]dioxo(methanol)molybdenum(VI) and [benzoyl-
       acetone benzoylhydrazonato(2-)]dioxo(triphenylphosphine oxide)molybdenum(VI).
       Z. anorg. allg. Chem. 621 (1995) 1275-1281.

30. W. Bansse, E. Ludwig, U. Schilde , E. Uhlemann and F. Weller: Ligand exchange reactions
of bis(acetylacetonato)dioxo-molybdenum(VI) and molybdenum hexacarbonyl.
J. Inorg. Biochem. 59 (1995) 730.

31. H. Kraudelt, U. Schilde and E. Uhlemann: ReCl₄(PPh₃)₂ - Reactions and structure.
Z. anorg. allg. Chem. 621 (1995) 1797-1799.

32. H. Kraudelt, G. Hinsche, U. Schilde und E. Uhlemann: Structure of bis(3-phenyl-4-benzoyl-
isoxazole-5-onato)copper(II).
Z. Naturforsch. 50b (1995) 1597-1600.

33. H. Kraudelt, E. Ludwig, U. Schilde und E. Uhlemann: Hydrolysis of trifluoroacetylacetone
salicylhydrazone. Structure of acetone salicylhydrazone.
Z. Naturforsch. 51b (1996) 563-566.

34. H. Poleschner and U. Schilde: The first structure of a vicinal (E)-fluoroselenoolefin:
(E)-(5-fluoro-4-octen-4-yl)dimethylselenonium picrate.
Acta Cryst. C52 (1996) 644-647.

35. H. Kraudelt, E. Ludwig, U. Schilde und E. Uhlemann: Molecular structures of tautomeric
forms of benzoylacetone benzoylhydrazone.
Z. Naturforsch. 51b (1996) 95-100.

36. E. Ludwig, U. Schilde, E. Uhlemann, H. Hartl und I. Brüdgam: Synthesis and structure of
       the copper complex [2-(2-hydroxy-5-methylphenyl)-6-(2-hydroxyphenyl)pyridinato(2-)]
       bis(pyridine)copper(II) and of the free ligand.
       Z. anorg. allg. Chem 622 (1996) 701-706.

37. U. Schilde, W. Mickler and E. Uhlemann: Crystal structure of bis(1-phenyldecane-1,3-
dionato)-copper(II), Cu(C₁₆H₂₁O₂)_2.
Z. Kristallogr. 211(1996) 503-505.

38. H. Hefele, E. Ludwig, U. Schilde and E. Uhlemann: Crystal structure of methoxyoxo[ben-
zoylacetone-salicylhydrazonato(2-)]vanadium(V), C₁₈H₁₇N₂O₅V.
Z. Kristallogr. 211 (1996) 655-656.

39. H. Poleschner, M. Heydenreich und U. Schilde: Fluoroselenenylation of acetylenes with
       xenon difluoride-diorganyl diselenides. Synthesis and structural elucidation of functiona-
       lized vicinal (E)-Fluoro(organylseleno)olefines.
       Liebigs Ann. Chem. 1996, 1187-1193.

40. T. Grobosch, U. Schilde, E. Uhlemann und L. Feistel: Separation of pentavalent arsenic
from groundwater by ion exchangers.
Chem. Technik 48 (1996) 203-211.

41. H. Kraudelt, U. Schilde, H. Hefele, E. Ludwig und E. Uhlemann: Titanium and vanadium
       complexes of 4-[1-(N'-benzoylhydrazino)-1-phenylmethylidene]-3-methyl-1-phenyl-
       pyrazol-5-one. Crystal structure of 4-[1-(N'-benzoylhydrazino)-1-phenylmethylidene]-
       3-methyl-1-phenylpyrazol-5-one.
       Z. Naturforsch. 51b (1996) 1240-1244.

42. W. Bansse, N. Jaeger, E. Ludwig, U. Schilde, E. Uhlemann, A. Lehmann and H. Mehner:
       Tin(IV) complexes with diacidic azo(hydrazono) compounds. Crystal structure of
       bis[4-(2'-hydroxyphenylazo)-3-methyl-1-phenylpyrazol-5-onato(2-)]tin(IV).
       Z. Naturforsch. 52b (1997) 237-242.

43. W. Klaeui, U. Schilde and M. Schmidt: (Fluoro)[³-hydrotris(3-R-5-methylpyrazol-1-yl)bo-
       rate]zinc(II): The First TpZnF Complexes; Convenient Precursors to Zinc Hydride Com-
       plexes.
       Inorg. Chem. 36 (1997) 1598-1601.

44. U. Schilde, W. Mickler and E. Uhlemann: Crystal structure of bis(1-phenyl-5-cyclohexyl-
pentane-1,3-dionato)copper(II), [Cu(C₁₇H₂₁O₂)₂].
Z. Kristallogr. 212 (1997) 65-66.

45. S. Sawusch, U. Schilde und E. Uhlemann: Ligand exchange reactions of ReCl4(PPh3)2
       with salicylaldehyde-2-hydroxy(mercapto)anil. Molecular structure of bis[salicylaldehyde-
       2-hydroxyanilato(2-)]rhenium(IV).
       Z. Naturforsch. 52b (1997) 61-64.

46. H. Hefele, H. Jancke, S. Sawusch, U. Schilde and E. Uhlemann: ¹³C-CP/MAS-NMR Spec-
       troscopy of tridentate diacidic ligands and their titanium(IV) chelates. Molecular structure of
       Bis[benzoylacetone-thiobenzoylhydrazonato(2-)]titanium(IV).
       Struct. Chem. 8 (1997) 211-216.

47. H. Kraudelt, U. Schilde, E. Uhlemann und F. Weller: Synthesis of tridentate ligands by
       cleavage of 3,5-diphenyl-1,2-dithiolium salts with (thio)benzoylhydrazine or 2-hydroxy-
       5-methylaniline. Structures of the corresponding nickel chelates.
       Z. Naturforsch. 52b (1997) 1043-1048.

48. S. Sawusch, U. Schilde, E. Uhlemann und F. Weller: Template reactions of 3,5-diphenyl-
1,2-dithiolium chloride with (thio)benzoylhydrazine and nickel or zinc acetate.
Z. Naturforsch. 52b (1997) 1139-1142.

49. S. Sawusch, U. Schilde, A. Lehmann and E. Uhlemann: Ligand exchange reactions of
       ReCl₄(PPh₃)₂with tridentate diacidic ligands having the donor set ONO(S). Molecular
       structures of the resulting oxo-rhenium(V) complexes.
       Inorg. Chim. Acta 268 (1998) 109-115.

50. W. Bansse, J. Fliegner, S. Sawusch, U. Schilde und E. Uhlemann: Salicylaldehyde-2-mercap-
       toanilato(2-)-2-hydroxyphenyl-benzthiazolato-nitrosyl-molybdän(II) - a chelate which simul-
       taneously contains an azomethine ligand and ist cyclic oxidation product.
       Inorg. Chim. Acta 269 (1998) 350-352.

51. T. Grobosch, S. Sawusch, U. Schilde und E. Uhlemann: Crystal structure of benzyl-(2-
hydroxyethyl)-dimethylammonium iodide, [C₁₁H₁₈NO]⁺ I^-.
Z. Kristallogr. 213 (1998) 173-174.

52. N. Jaeger und U. Schilde: Molecular mechanics calculations on chelates of titanium(IV),
       vanadium(IV/V), copper(II), nickel(II), molybdenum(IV/V), rhenium(IV/V) and tin(IV)
       with di- and tridentate ligands using the new extensible systematic force field (ESFF): an
       empirical study.
       Struct. Chem. 9 (1998) 77-93.

53. H. Kraudelt, U. Schilde and E. Uhlemann: Crystal structure of bis(1-thioxo-1,3-diphenyl-3-
phenylamino-2-propeneato)nickel(II) dichloromethane solvate, Ni(C₂₁H₁₆NS)2CH₂Cl₂.
Z. Kristallogr. 213 (1998) 175-176.

54. H. Kraudelt, U. Schilde and E. Uhlemann: Crystal structures of 1-methylamino-D-1-deoxy-
glucitol, C₇H₁₇NO₅ and 1-methylamino-D-1-deoxy-glucitol hydrochloride, C₇H₁₈ClNO₅.
Z. Kristallogr. 213 (1998) 177-179.

55. S. Sawusch, U. Schilde, A. Lehmann und E. Uhlemann: Ligand exchange reactions of
       ReCl₄(PPh₃)₂, ReOCl₃(PPh₃)₂ and NiCl₂(PPh₃)₂with acetylacetone thiobenzoylhydrazone.
       An unexpected template reaction at the ReO³⁺ core. Molecular structures of the resulting
       oxorhenium(V) and nickel complexes.
       Inorg. Chim. Acta 277 (1998) 219-224.

56. W. Bansse, J. Fliegner, S. Sawusch, U. Schilde und E. Uhlemann: Dioxomolybdenum(VI)
complexes with tridentate diacidic ligands.
Z. Naturforsch. 53b (1998) 689-693.

57. W. Mickler, A. Reich, S. Sawusch, U. Schilde and E. Uhlemann: Aquabis(3-methyl-4-octa-
       noyl-1-phenyl-5-pyrazolonato-O,O')zinc(II) and Bis(ethanol-O)bis(3-methyl-1-phenyl-
       4-stearoyl-5-pyrazolonato-O,O')cadmium(II).
       Acta Cryst. C54 (1998) 776-779.

58. W. Bansse, J. Fliegner, S. Sawusch, U. Schilde und E. Uhlemann: Redox reactions
       of molybdenum compounds with bis(2-salicylideneaminophenyl)disulfide. Crystal
       structure of (salicylaldehyde-2-mercaptoanilato(2-))(triphenylphosphine oxide)
       dioxomolybdenum(VI).
       Z. Naturforsch. 53b (1998) 275-278.

59. R. Benassi, A. Bregulla, A. Friedrich, D. Henning, M. Heydenreich, W. Mickler,
       E. Kleinpeter, G. Kempter, U. Schilde and F. Taddei: NMR spectroscopic and theoretical
       structural study of 5-exo-methylene-substituted hydantoins.
       J. Mol. Struct. 441 (1998) 47-62.

60. S. Sawusch and U. Schilde: Crystal structure of bis(triethylammonium)-hexachloro-
rhenate(IV), (C₆H₁₆N)₂ReCl₆.
Z. Kristallogr. 214 (1999) 79-80.

61. S. Sawusch und U. Schilde: Crystal structure of dichloro-[4,4,4-trifluoro-1-(2'-thienyl)bu-
tane-1,3-dionato]-bis(triphenylphosphine)rhenium(III), [Re(C₄₄H₃₄Cl₂F₃O₂P₂S].
Z. Kristallogr. 214 (1999) 81-82.

62. S. Sawusch, N. Jäger, U. Schilde and E. Uhlemann: Ligand exchange reactions of
       ReOCl₃(PPh₃)₂ with tridentate diacidic ligands with the donor set ONO(N). Molecular
       and electronic structures of the resulting oxo-rhenium(V) complexes.
       Struct. Chem. 10 (1999) 105-119.

63. U. Schilde und S. Sawusch: Crystal structure analysis with x-rays.
Praxis der Naturwissenschaften. Chemie 48 (1999) 2-12.

64. T. Grobosch, W. Mickler und U. Schilde: Abtrennung von Arsen und anderer Schwermetalle
       mit imprägnierten Adsorberpolymeren. Teil I: Synthese der Imprägnierungsmittel und Ab-
       trennung von Arsen.
       Chem. Technik (an die Redaktion gesandt)

65. T. Grobosch, B. Tiersch, L. Feistel und U. Schilde: Abtrennung von Arsen und ande-
       rer Schwermetalle mit imprägnierten Adsorberpolymeren. Teil II: Abtrennung von Blei,
       Kupfer, Nickel und Zink.
       Chem. Technik (an die Redaktion gesandt)

66. D. Lenz, H. Hartl, G. Hinsche, S. Sawusch, U. Schilde und E. Uhlemann: Molecular struc-
       tures of the zinc chelates with thiodibenzoylmethane, 3-methyl-1-phenyl-4-thiobenzoyl-
       pyrazol-5-one and 4-benzoyl-3-methyl-1-phenyl-pyrazol-5-thione.
       Acta Cryst. (in Vorbereitung)

67. S. Sawusch und U. Schilde: Ligand exchange reactions of NiCl₂(PPh)₂ with O(S)NS ligands.
Z. Naturforsch.54b (1999) 881-886.

68. W. Bansse, J. Fliegner, S. Sawusch, U. Schilde und E. Uhlemann: Ligand exchange reactions
       of bis(acetonitril)-molybdenum(IV) chloride with triadentate diacidic ligands.
       Crystal structure of (salicylaldehyde-benzoylhydrazonato)aqua-dioxomolybdenum(VI).
       Z. Naturforsch. (in preparation)

Lectures on the occasion of Chemiedozententagungen:

Rostock 1984: Complex formation and extraction of nickel with 7-alkyl-quinolin-8-ols.
Güstrow 1991: Extraction of boric acid from brines.
Siegen 1994: Separation of oxoanions with a special chelating resin.
Essen 1998: Separation of arsenic and other heavy metals using impregnated resins.
Adsorberpolymere.