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| Publications |
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2012
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(72)
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Schmidt, B.; Krehl, S.; Jablowski, E. Assisted tandem catalytic RCM-aromatization in the synthesis of pyrroles and furans. Org. Biomol. Chem. 2012. DOI |
(71)
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Schmidt, B.; Krehl, S.; Sotelo-Meza, V. Synthesis of Chromanes through RCM-Transfer Hydrogenation. Synthesis 2012. DOI
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(70)
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Schmidt, B.;
Kunz, O. α,β-Unsaturated δ-Valerolactones through RCM-Isomerization Sequence. Synlett 2012, 23, 851-854. DOI
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(69)
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Schmidt, B.; Elizarov, N. Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions. Chem. Commun. 2012, 48, 4350-4352. DOI
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(68)
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Schmidt, B.; Krehl, S.; Kelling, A.; Schilde, U. Synthesis
of 8-arylsubstituted coumarins based on ring closing metathesis and
Suzuki-Miyaura coupling: synthesis of a furyl coumarin natural product
from Galipea panamensis. J. Org. Chem.
2012, 77, 2360-2367. DOI
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(67)
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Schmidt, B.;
Kunz, O. One-Flask Tethered Ring Closing Metathesis–Electrocyclic Ring
Opening for the Highly Stereoselective Synthesis of Conjugated
Z/E-Dienes. Eur. J. Org. Chem.
2012, 1008–1018. DOI
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| 2011 |
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(66)
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Duvinage, B.; Schmidt, B.; Kabutz, K. Kein Opium für die Feier, denn... Praxis der Naturwissenschaften – Chemie in der Schule 2011, 60(7), 36-41.
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(65)
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Schmidt,
B.; Geißler, D. Olefin-Metathesis-Based Synthesis of Furans by an
RCM/Deprotonation/Phosphorylation Sequence and Their Diels–Alder
Reactions. Eur. J. Org. Chem.
2011, 7140–7147. DOI |
| (64) | Schmidt,
B.; Geißler, D. Ru- and Pd-Catalysed Synthesis of 2-Arylfurans by One-Flask Heck Arylation/Oxidation. Eur. J. Org. Chem.
2011, 4814–4822. DOI | | (63) | Schmidt, B.; Krehl, S. A single precatalyst Tandem
RCM-allylic oxidation sequence. Chem. Commun. 2011, 5879–5881. DOI | | (62) | Schmidt, B.; Hölter, F. Suzuki-Miyaura coupling
reactions with Phenol diazonium salts. Org. Biomol. Chem. 2011, 9, 4919–4920. DOI | | (61) | Schmidt,
B.; Hölter, F.; Kelling, A.; Schilde, U. Pd-catalyzed arylation reactions with phenol diazonium salts: application in the synthesis of diarylheptanoids J. Org. Chem. 2011, 76, 3357–3365. DOI | | (60) | Schmidt, B.; Berger, R.; Kelling, A.; Schilde, U. Pd-catalyzed [2+2+1] coupling of alkynes and arenes: phenol diazonium salts as mechanistic trapdoors. Chem. Eur. J. 2011, 17, 7032–7040. DOI |
| (59) |
Schmidt,
B.; Staude, L. Desymmetrization of (R,R)-Hexa-1,5-diene-3,4-diol via
Monofunctionalization and Rhodium-Catalyzed Allylic Substitution J. Org. Chem. 2011, 76, 2220–2226. DOI |
| (58) | Buddrus, J.; unter Mitarbeit von
Schmidt, B. „Grundlagen der Organischen Chemie“ de Gruyter Verlag,
Berlin, 2011. | | (57) | Schmidt,
B.; Schanzenbach, D. Allyl ether (2011), Encyclopedia of Reagents for
Organic Synthesis (Online), John Wiley & Sons Ltd.,
www.mrw.interscience.wiley.com/eros/, [March 18th 2011].
| | (56) | Schmidt,
B.; Staude, L.; Kelling, A.; Schilde, U. A Cross-Metathesis-Conjugate
Addition Route to Enantiopure γ-Butyrolactams and γ-Lactones from a C2-Symmetric Precursor. Eur. J. Org. Chem. 2011, 1721–1727. DOI | | (55) | Reznichenko, A.; Emge, T.; Audörsch, S.; Klauber, E.; Hultzsch, K.; Schmidt,
B. Group 5 Metal Binaphtholate Complexes for Catalytic Asymmetric
Hydroaminoalkylation and Hydroamination/Cyclization. Organometallics 2011, 30 , 921–924. DOI |
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| 2010 |
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| | (54) | Krehl, S.; Geißler, D.; Hauke S.; Kunz, O.; Staude, L.; Schmidt, B. The catalytic performance of Ru-NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand. Beilstein J. Org. Chem. 2010, 6, 1188–1198. DOI | | (53) | Schmidt, B.; Hölter, F.; Berger, R. Mizoroki-Heck Reactions with 4-Phenoldiazonium Salts. Adv. Synth. Catal. 2010, 352, 2463–2473. DOI |
| (one of the most accessed articles in 2011) |
| (52) |
Schmidt, B.; Werner, F.; Kelling, A.;
Schilde, U. The reaction of
3,4-dihydro-2H-pyran with oxalyl chloride: formation and crystal
structure analysis of an unexpected bicyclic product. J. Heterocyclic Chem. 2010, 47, 1171–1175. DOI |
| (51) |
Schmidt, B.; Kunz,
O.; Biernat, A. Total Synthesis of (–)-Cleistenolide. J. Org. Chem. 2010, 75, 2389–2394. DOI |
| (one of the most downloaded articles in 2010) |
| (50) |
Schmidt,
B.; Geißler, D. Ring-Closing Metathesis of Acrylates: A Comparative
Study. ChemCatChem
2010,
2, 423–429. DOI |
| (49) |
Schmidt,
B.; Berger, R.; Hölter, F. Functionalized alkoxy arene diazonium salts
from paracetamol. Org.
Biomol. Chem. 2010,
8,
1406–1414. DOI |
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| 2009 |
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| | (48) | Schmidt,
B.; Berger, R.; Hölter, F.; Böge, N.; Kreipl, A. Process for production
and applications of phenolic diazonium salts. Eur. Patent Appl.
EP09158489, 2009. |
| (47) |
Schmidt,
B.; Staude, L. Ring-Size-Selective Enyne Metathesis as a Tool for
Desymmetrization of an Enantiopure C2-Symmetric Building Block. J.
Org. Chem. 2009, 74,
9237–9240. DOI |
| (46) |
Schmidt,
B.;
Hölter, F. A stereodivergent synthesis of all stereoisomers of
centrolobine: control of selectivity by a protecting group
manipulation. Chem. Eur. J. 2009,
15,
11948–11953. DOI |
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| 2008 |
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| (45) |
Schmidt,
B.;
Biernat A. Synthesis of 3-Deoxy Glycals via Tandem Metathesis Sequences
and Their Use in an Intermolecular Heck Arylation. Eur. J.
Org.
Chem. 2008, 5764–5769. DOI |
| (44) |
Schmidt,
B.;
Hölter, F. Process for preparing aromatic diazonium salts from aromatic
amides. WO 2008055927, 2008. |
| (43) |
Schmidt,
B.;
Biernat, A. The Tandem Ring-Closing Metathesis-Isomerization Approach
to 6-Deoxyglycals. Chem. Eur. J. 2008,
14,
6135–6141. DOI |
| (42) |
Schmidt, B; Biernat, A. Tandem
RCM-isomerization
approach to glycals of desoxyheptoses from a common precursor. Org. Lett.
2008,
10,
105–108. DOI |
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| 2007 |
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| (41) |
Schmidt,
B.;
Biernat, A. Synthesis of enantiomerically pure dihydrofurans and
dihydropyrans from common precursors using RCM and Tandem
RCM-isomerization. Synlett 2007,
2375–2378. DOI |
| (40) |
Schmidt, B.; Nave, S.
Synthesis of
Dihydrofurans and Dihydropyrans with Unsaturated Side Chains Based on
Ring Size-Selective Ring-Closing Metathesis. Adv. Synth. Catal.
2007,
349,
215–230. (Special issue on olefin
metathesis, Fürstner, A.; Grubbs
R. H.; Schrock, R. R., eds.) DOI |
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| 2006 |
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| (39) |
Schmidt,
B.; Staude, L. Unexpected hydrogen transfer in the course of olefin
metathesis-isomerization based syntheses of chiral 2,3-dihydropyrans. J. Organomet. Chem.
2006,
690, 5218–5221. DOI |
| (38) |
Schmidt,
B.; Nave, S. Stereoselective syntheses of enantiomerically pure
2,5-disubstituted dihydropyrans based on olefin metathesis. J. Org. Chem. 2006, 71,
7364–7369. DOI
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| (37) |
Schmidt,
B.; Nave, S.
Control of Ring Size Selectivity by Substrate directable RCM. Chem. Commun.
2006,
2489-2491. highlighted in:
Nachr. Chemie 2006,
54,
1184. DOI |
| (36) |
Schmidt, B.;
Hermanns, J. Ring closing
metathesis of substrates containing more than two C-C-double bonds:
rapid access to functionalized heterocycles. Curr. Org. Chem.
2006, 10,
1363–1396 (Review). DOI |
| (35) |
Schmidt,
B. Olefin metathesis and isomerization: From undesired side reactions
to useful synthetic methodology. J. Mol. Catal. A 2006, 254,
53–57. DOI |
| (34) |
Schmidt, B.
Connecting catalytic cycles by organometallic transformations in situ:
Novel perspectives in the olefin metathesis field. Pure
Appl. Chem. 2006, 78,
469–476. DOI |
| (33) |
Schmidt,
B.; Nave S.
Palladium-Catalyzed O-Allylation of α-Hydroxy
Carbonyl Compounds. Adv. Synth. Catal. 2006,
348, 531–537. DOI |
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| bis 2005 |
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| (32) |
Schmidt,
B.; Pohler,
M. Ruthenium-catalyzed tandem ring closing metathesis (RCM)-atom
transfer radical cyclization (ATRC) sequences. J. Organomet.
Chem. 2005, 690,
5552–5555. highlighted in: Nachr.
Chemie 2006, 54, 98. DOI |
| (31) |
Schmidt,
B.
Ruthenium-Catalyzed Olefin Metathesis Double-Bond Isomerization
Sequence. J. Org. Chem. 2004,
69,
7672–7687. DOI |
| (30) |
Schmidt,
B.;
Hermanns J. Olefin Metathesis directed toward Organic Synthesis:
Principles and Applications. Top. Organomet.
Chem. 2004, 13, 223–267
(Invited review). DOI |
| (29) |
Schmidt,
B. Tandem
Isomerization/Claisen Rearrangement of Diallyl- and
Allylhomoallylethers: In Situ Conversion of Grubbs’ catalyst to a Ru-H
Species. Synlett 2004,
1541–1544. DOI |
| (28) |
Schmidt
B. In situ
conversion of a Ru metathesis catalyst to an isomerization catalyst.
Chem. Commun. 2004, 742-743. highlighted
in: Green
Chemistry 2004,
6, G58. DOI |
| (27) |
Schmidt,
B. Catalysis at the interface of ruthenium-carbene and
ruthenium-hydride chemistry: organometallic aspects and applications to
organic synthesis. Eur. J. Org. Chem. 2004,
1865–1881 (Review). DOI |
| (26) |
Schmidt,
B.; Pohler, M.; Costisella, B. Ring closing olefin metathesis and
radical cyclization as competing pathways. J. Org. Chem.
2004, 69,
1421–1424. DOI |
| (25) |
Schmidt,
B. Rutheniumkatalysierte Cyclisierungen: mehr als "nur"
Olefinmetathese! Angew. Chem. 2003, 115, 5146-5149; Ruthenium-catalysed
cyclizations: More than just olefin metathesis! Angew. Chem.
Int.
Ed. 2003, 42, 4996–4999.
("Highlight") DOI |
| (24) |
Schmidt,
B; Pohler, M. Tandem olefin metathesis-hydrogenation at ambient
temperature: Activation of Ruthenium carbene complexes by addition of
hydrides. Org. Biomol. Chem. 2003,
1,
2512–2517. DOI |
| (23) |
Schmidt, B. Heck
arylation of
cyclic enol ethers with aryldiazonium salts: Regio- and stereoselective
synthesis of arylated oxacycles. Chem. Commun. 2003,
1656–1657. DOI |
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(22)
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Schmidt,
B. An
olefin metathesis/double bond isomerization sequence catalyzed by in
situ generated ruthenium–hydride species. Eur. J.
Org. Chem. 2003, 816–819. DOI
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(21)
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Wildemann,
H.;
Dünkelmann, P.; Müller, M.; Schmidt, B. A short olefin metathesis-
based route to enantiomerically pure arylated dihydropyrans and a,b-unsaturated d- valero lactones. J.
Org. Chem. 2003, 68,
799–804. DOI
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| (20) | Schmidt,
B.;
Pohler, M.; Costisella, B.; Di- and tetrahydropyrans with orthogonally
protected hydroxymethyl side chains. A synthetic route and the
structure elucidation of an unexpected acetal cleavage product. Tetrahedron
2002, 58,
7951–7958. DOI |
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(19)
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Schmidt,
B.;
Wildemann, H. Synthesis of enantiomerically pure divinyl- and
diallylcarbinols. J. Chem. Soc.-Perkin Trans. 1 2002,
1050–1060. DOI
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(18)
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Schmidt,
B.;
Costisella, B.; Roggenbuck, R.; Westhus, M.; Wildemann, H.; Eilbracht,
P. Combining ring-closing metathesis and hydroformylation strategies:
A novel approach to spirocyclic g-butyrolactones.
J. Org. Chem. 2001,
66,
7658–7665. DOI
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| (17) |
Schmidt,
B. A de
novo synthesis of 2,6-dideoxy-C-aryl glycosides based on ring closing
metathesis and diastereoselective epoxide cleavage/anomerization
reactions. Org. Lett. 2000, 2,
791–794. DOI
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(16)
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Schmidt,
B.;
Westhus, M. Diastereoselectivity in a ring closing metathesis reaction
with a remote stereogenic centre leading to quaternary dihydropyrans. Tetrahedron
2000, 56,
2421–2426. DOI
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(15)
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Schmidt,
B.;
Wildemann, H. Single and double ring closing metathesis in the
formation of dihydropyrans and bisoxacyclic systems with a quaternary
centre. J. Chem. Soc.-Perkin Trans. 1 2000,
2916–2925. DOI
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(14)
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Schmidt,
B.;
Wildemann, H. Diastereoselective ring-closing metathesis in the
synthesis of dihydropyrans. J. Org. Chem. 2000,
65,
5817–5822. DOI
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(13)
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Schmidt,
B.;
Wildemann, H. A synthesis of densely functionalized 2,3-dihydropyrans
using ring-closing metathesis and base-induced rearrangements of
dihydropyran oxides. Eur. J. Org. Chem. 2000,
3145–3163. DOI
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(12)
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Schmidt,
B.
Base-induced rearrangement of dihydropyran oxides: A novel synthesis of
cyclic enol ethers with a hydroxy-function in the allylic position. Tetrahedron
Lett. 1999, 40,
4319–4320. DOI
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(11)
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Schmidt,
B.
Epoxide opening reactions of aryl substituted dihydropyran oxides:
regio- and stereochemical studies directed towards
deoxy-aryl-C-glycosides. J. Chem. Soc.-Perkin Trans. 1 1999,
2627–2637. DOI
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(10)
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Schmidt,
B.;
Wildemann, H. Synthesis of functionalized 2,3- and 3,4-dihydropyrans
starting from a-hydroxycarboxylic
esters
via RCM. Synlett 1999,
1591–1593. DOI
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(9)
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Hermanns,
J.;
Schmidt, B. Five- and six-membered silicon-carbon heterocycles. Part
2. Synthetic modifications and applications of silacycles. J.
Chem.
Soc.-Perkin Trans. 1 1999, 81–102
(Review). DOI
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(8)
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Kocienski,
P. J.;
Brown, R. C. D.; Pommier, A.; Procter, M.; Schmidt, B. Synthesis of
Salinomycin. J. Chem. Soc.-Perkin Trans. 1 1998,
9–39. DOI
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(7)
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Hermanns,
J.;
Schmidt, B. Five- and six-membered silicon-carbon heterocycles. Part
1. Synthetic methods for the construction of silacycles. J.
Chem.
Soc.-Perkin Trans. 1 1998, 2209–2230
(Review). DOI
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(6)
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Schmidt,
B.;
Sattelkau, T. Ring closing metathesis as the key step in the synthesis
of furan-substituted C-aryl glycosides. Tetrahedron
1997,
53, 12991–13000. DOI
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(5)
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Herberich,
G. E.;
Schmidt, B.; Schmitz, A.; Fischer, A.; Riedel, M.; Herrmann, H.-F.;
Özdemir, D. Preparation of transition metal compounds with
boratabenzene ligands as olefin polymerization catalysts. (Hoechst AG),
GE 19, 624,466, 1996; Chem. Abstr.
1997, 127,
P136151y.
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(4)
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Herberich,
G. E.;
Rosenplänter, J.; Schmidt, B.; Englert, U. Borabenzene derivatives
.24. From lithium 1-methylboratabenzene to 2-mono- and
2,2-disubstituted 1-methyl- 1,2-dihydroborinines with Me3Si,
Me3Ge, Me3Sn, and Me3Pb
substituents.
Degenerate sigmatropic rearrangements with exceptionally low barriers
and the structure of 2-(Me3Sn)C5H5BMe.
Organometallics 1997,
16,
926–931. DOI
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| (3) |
Schmidt,
B.;
Kocienski, P.; Reid, G. A synthesis of oxolenes and furans via
oxacyclopentylidene chromium and molybdenum complexes. Tetrahedron
1996,
52, 1617–1630. DOI
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| (2) |
Herberich,
G. E.;
Schmidt, B.; Englert, U. Borabenzene Derivatives .22. Synthesis of
Boratabenzene Salts from 2,4-Pentadienylboranes - Structure of [NMe3Ph][C5H5BMe].
Organometallics 1995,
14,
471–480. DOI
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| (1) |
Herberich,
G. E.;
Schmidt, B.; Englert, U.; Wagner, T. Borabenzene Derivatives .21.
2,4-Pentadienylboranes as Key Intermediates of a Novel Route to
Boracyclohexadienes and Boratabenzenes - Structure of [Li(Tmpda)](C5H5BNMe2).
Organometallics 1993,
12,
2891–2893. DOI
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