S. S. Mondal, A. Bhunia, I. A. Baburin, C. Jäger, A. Kelling, U. Schilde, G. Seifert, C. Janiak, H.-J. Holdt
Gate Effects in a Hexagonal Zinc-Imidazolate-4-amide-5-imidate Framework with Flexible Methoxy Substituent and CO2 Selectivity
Chem. Comm. 2013, 49, 7599
DOI: 10.1039/C3CC42156B
A new imidazolate-4-amide-5-imidate based MOF, IFP-7 is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.
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