Publikation

S.S. Mondal, A. Bhunia, A, Kelling, U. Schilde, C. Janiak, H.-J. Holdt
Giant Zn14 Molecular Building Block in Hydrogen-Bonded Network with Permanent Porosity for Gas Uptake
J. Am. Chem. Soc. 2014, 136, 44
DOI: 10.1021/ja410595q
In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn14(L2)12(O)-(OH)2(H2O)4] molecular building block (MBB) with a Zn6 octahedron inscribed in a Zn8 cube. The MBBs connect by amide−amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N2, CO2, CH4, and H2 gas sorption.
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