M. Hechenbichler, A. Laschewsky, M. Gradzielski
Poly(N,N-bis(2-methoxyethyl)acrylamide), a Thermo-responsive Nonionic Polymer Combining the Amide and the Ethyleneglycolether Motifs
Colloid Polym. Sci. 2021, 299, 205-219
DOI: 10.1007/s00396-020-04701-9
Poly(N,N-bis(2-methoxyethyl)acrylamide) (PbMOEAm) featuring two classical chemical motifs from non ionic water soluble polymers, namely the amide and ethyleneglycolether moieties, was synthesized by Reversible Addition Fragmentation Transfer (RAFT) polymerization. The thermoresponsive behavior in aqueous solution, exhibiting a lower critical solution temperature (LCST), was investigated. A series of homo and block copolymers with functional end-groups were prepared accordingly, and their capability for acting as \"smart\" surfactants was explored.
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