Publikation

Sand, P.; Schmidt, B.
Pd-Catalyzed Oxidative Sulfoalkenylation of Acetanilides and Traceless Removal of the Catalyst Directing Group
ChemistrySelect 2021, 6, 3563-3567
DOI: 10.1002/slct.202101009
The Pd-catalyzed oxidative Heck-reaction has been applied to vinylsulfonyl compounds, using acetamides as catalyst directing groups. The traceless removal of the catalyst directing group through deacetylation-diazotation-coupling sequence was exemplified and furnishes 1,2-dialkenylated arenes.The Pd-catalyzed oxidative Heck-reaction has been applied to vinylsulfonyl compounds, using acetamides as catalyst directing groups. The traceless removal of the catalyst directing group through deacetylation-diazotation-coupling sequence was exemplified and furnishes 1,2-dialkenylated arenes.
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