P. Wessig, R. Merkel, P. Müller
Articulated rods – a novel class of molecular rods based on oligospiroketals (OSK)
Beilstein J. Org. Chem. 2015, 11, 74-84
DOI: 10.3762%2Fbjoc.11.11
We developed a new type of molecular rods consisting of two (or more) rigid units linked by a flexible joint. Consequently we called these constructs articulated rods (ARs). The syntheses of ARs were carried out by a flexible and modular approach providing access to a number of compounds with various functionalizations in terminal positions. First applications were presented with pyrene, cinnamoyl and anthracenyl labelled ARs.
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